Journal of the American Chemical Society
September 24 2024
Reserving Electrons in Cofactor Decorated Coordination Capsules for Biomimetic Electrosynthesis of α-Hydroxy/amino Esters
Huali Wang,† Yu Zhang,† Guanfeng Ji,† Jianwei Wei,† Liang Zhao,†,* Cheng He,† and Chunying Duan†,§,*
† State Key Laboratory of Fine Chemicals, Frontier Science Center for Smart Materials, Dalian University of Technology, Dalian 116024, P. R. China.
§ State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China.
10.1021/jacs.4c08547
A cobalt-based coordination capsule decorated with a NADH mimic was elaborately formulated as an electron reservoir for accepting a single electron consecutively to efficiently regenerate the NADH mimic for α-hydroxy/amino esters production through pseudo-intramolecular hydride transfer, thereby providing insights into the electron transfer regulation for biomimetic electrosynthesis.
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