European Journal of Inorganic Chemistry
26 October 2021
High Quality of a Perchlorate-Based Hybrid Perovskite-Type Cage-Like Single Crystal – Evidence of Temperature-Induced Distinct Dielectric Transition
Yi-Fang Huang, Lin Xiang, Yan Feng, Zhen An, Le-Ping Miao, Jian-Rong Li,* Heng-Yun Ye, Chao Shi
Chaotic Matter Science Research Center, Jiangxi University of Science and Technology, Ganzhou, Jiangxi, 330000 China
10.1002/ejic.202100899
The Cover shows the first three-dimensional Ba-based ABX3 type organic-inorganic hybrid perovskite compound (HTZ)[Ba(ClO4)3] (HTZ = thiazolium cation) with Ba2+ nodes and ClO4− linkers. The compound undergoes two continuous reversible phase transitions at different temperatures accompanied by a change in dielectric constant, which shows the cyclic nature of the switching effect of the material. More information can be found in the Full Paper by J.-R. Li, C. Shi and co-workers.
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